Electrochemistry, electrocatalysis, activation of hydrocarbon molecules, surface mediated reactions, in situ spectroscopies for mechanistic investigations
861 Natural Sciences Complex
Buffalo NY, 14260
Phone: (716) 645-4285
Fax: (716) 645-6963
Electrochemical reaction is a powerful tool to manipulate the flow of electron, activate chemical reactions, control reaction intermediates and steer the reaction selectivity. We are working to identify electrochemically active site with computational modelling and design catalysts with inorganic, hybrid metal/metal oxide, or metal/organic material to achieve selective chemical transformations. Our targets are to utilize small molecule as building materials, such as CO2, H2O, N2, methane or sugar, to explore new reactions in electro- inorganic and organic synthesis.
The goal of this research program is to understand how chemical bonds are formed or broken and how to control them selectively in an electrochemical process. These efforts will lead us to new chemical processes with lowered carbon footprint and environmental impacts.
Electroanalytical Tools and Methods
There are many forces at play during an electrochemical reaction – surface binding, solvation, H bonding, van der Waals, electrostatic and more. We are interested in how these chemical interactions affect the chemical outcome of a reaction. To this end, we employ a combination of electroanalytical and spectroscopic techniques to monitor the concentration, orientation and time evolution of surface species during a reaction. Statistical and machine learning approach are also used to analyze the electrochemical and spectroscopic data to enhance our understanding of the electrode-electrolyte interface. The goal of this research program is to develop new tools and methods to study the reaction kinetic and mechanism of energy related catalytic processes.